鸭儿湖地区六氯环己烷的残留动态与长期归宿

DYNAMICS AND LONG-TERM FATE OF RESIDUAL HEXACHLOROCYCLOHEXANE (HCH) IN VARIOUS TYPES OF ENVIRONMENT IN YA-ER LAKE AREA, CHINA

  • 摘要: 在1990-1993年期间,研究了历史上曾被HCH严重污染的鸭儿湖地区的水生态系统和陆生生态系统中HCH的残留动态与归宿,获得了HCH在各种不同环境条件下的残留动态方程与环境半衰期。结果表明:鸭儿湖底泥是HCH长期残留的主要归宿。尽管HCH已禁用十几年,目前该地区环境中HCH的残留已降至亚ng/g级水平,然而它在淡水食物链中仍然存在很高的生物积累。残留的HCH在各种环境中的分布和转移均与该地区有机质含量呈正相关。目前环境中HCH残留的主要异构体是β-HCH.同时各种环境中HCH的残留动态可用指数方程来表示,其半衰期在四种不同环境中的顺序为:水<土壤<稻田泥<底泥。

     

    Abstract: A study on dynamics and long-term fate of residual hexachlorocyclohexane(HCH)in aquatic and terrestrial environments in Ya-Er Lake Area,heavily pollutedby HCH historically, was carried out during the period from 1990-1993. Theconcentration Kinetics and half-lived bine of HCH-residues in four differentenvironments were obtained. The results show that sediment is the primaryaccumulation site for the long-term fate of HCH-residues. Despite HCH was bannedfor more than ten years in Ya-Er Lake Area,the bioaccumulation of HCH-residue infreshwater food chain was still high (BCF=104 in fish liver). The distribution andmobility of HCH-residues are correlated with the organic matter positively. TheHCH-residue in the current environmentin that area is mainlyβ-HCH. Meanwhile, aseries of model exponential equations are used for describing dynamics of HCH-residues. From these equations, the half-lived time calculated and the order infour different environments are:water soil mud of paddy field sediment.

     

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